Methanolysis of sunflower oil using gem-diamines as active organocatalysts for biodiesel production Original Research Article

Diamines with neighbour nitrogen atoms have been used as base organocatalysts in the transesterification of sunflower oil with methanol at different temperatures. Several gem-diamines have been studied: dipiperidine-methane (diamine A), di(3-methylpiperidine)-methane (diamine B) and di(3,5-dimethylpiperidine)-methane (diamine C) using a MeOH/oil molar ratio 10/1, in a batch reactor. It has been found that the catalytic activity follows A > B > C, whatever the reaction temperature used. This ranking is inversely correlated to their intrinsic basicity (C > B > A), indicating that for biodiesel production the intrinsic basicity is not the only catalyst factor controlling the activity but the adequate steric ability to abstract and to release back the proton is necessary for an efficient transesterification process. Besides, dipiperidinephenyl-methane, a functionalized derivative of diamine A, has proved to be a promising candidate for heterogeneization.