Title of article
Visible light-driven aerobic oxidation catalyzed by a diiron(IV) μ-oxo biscorrole complex Original Research Article
Author/Authors
Rui Zhang، نويسنده , , Eric Vanover، نويسنده , , Tse-Hong Chen، نويسنده , , Helen Thompson، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
6
From page
95
To page
100
Abstract
Under visible light irradiation, the diiron(IV) μ-oxo-bis(5,10,15-tripentafluorophenylcorrole) complex catalyzes the aerobic oxidations of hydrocarbons in sequences employing photo-disproportionation reactions. The active oxidant, highly reactive corrole-iron(V)-oxo species, can be detected in real time via laser flash photolysis methods.
Keywords
Iron corrole , aerobic oxidation , Visible light , Photo-disproportionation
Journal title
Applied Catalysis A:General
Serial Year
2013
Journal title
Applied Catalysis A:General
Record number
1157496
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