Title of article :
Synthesis of hollow spherical silica with MCM-41 mesoporous structure
Author/Authors :
Xu، Jun نويسنده , , Han، Shuhua نويسنده , , Hou، Wanguo نويسنده , , Li، Zhengmin نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2004
Pages :
-1285
From page :
1286
To page :
0
Abstract :
Hollow spherical mesoporous silica was synthesized by using sodium silicate as a precursor and a low concentration of cetyltrimethylammonium bromide (CTAB) (0.154 mol dm–3). The resulting hollow spherical particles were characterized with scanning electron microcopy (SEM), small-angle X-ray diffraction (SXRD), transmission electron microscopy (TEM), and N2 gas adsorption and desorption techniques. The results showed that regular spherical mesoporous silica could be obtained only if the molar ratio of propanol to CTAB was in the range of approximately 8:1–9:1. The spherical particles were hollow (inside), and the shell consisted of smaller particles with a pore structure of hexagonal symmetry. With an increase of the molar ratio of propanol to CTAB, the distance (a value) between centers of two adjacent pores increased, and the pore structure of mesoporous silica became less ordered. N2 adsorption–desorption curves revealed type IV isotherms and H1 hysteresis loops; with an increase of the molar ratio of propanol to CTAB, the pore size with Barrett–Joyner–Halenda (BJH) diameter of the most probable distribution decreased, but the half peak width of the pore size distribution peak increased
Journal title :
COLLOID & POLYMER SCIENCE
Serial Year :
2004
Journal title :
COLLOID & POLYMER SCIENCE
Record number :
116137
Link To Document :
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