Predictions of the Joule–Thomson inversion curves for polar and non-polar fluids from the SAFT-CP equation of state Original Research Article

In this work, we calculate the Joule–Thomson inversion curves of some non-polar fluids, including argon, nitrogen, oxygen, carbon dioxide, n-alkanes (C1–C4), ethene, acetylene, benzene and toluene and some polar fluids, including hydrogen sulfide, ammonia, acetone and ethyl ether from the SAFT-CP equation of state. Comparisons with correlated experimental data and reference equation of state indicate that this molecular based equation of state gives good prediction for non-polar fluids. For polar fluids, the predictions of the low-temperature branch are satisfied; but, unfortunately, due to lack of isenthalpic data for high-pressure–high-temperature gas condensate, the reliability of model predictions could not be completely verified. In this work, the performance of some cubic equations of state in predicting the Joule–Thomson inversion curves is also compared with SAFT-CP equation of state.