Abstract :
Excess molar enthalpies, HmE, of binary mixtures containing (S)-(−)-limonene+α-pinene, + β-pinene, or+p-cymene were determined using a flow microcalorimeter in the range 288.15–313.15 K, and at atmospheric pressure. The HmE are always positive, not exceeding 114 J mol−1, and curves show a symmetrical trend. The temperature dependence of the calorimetric data is slight. Results were correlated to the Redlich–Kister polynomial and the adjustable parameters were determined by the least-squares method. Results were also interpreted by an extended modified cell model of Prigogine.
