Excess molar volumes of binary mixtures of alkanols with ethyl acetate from 298.15 to 323.15 K

Excess molar volumes VE have been investigated from density ρ measurements using vibrating-tube digital densimeter DMA 60/602 for binary mixtures of methanol, 1-propanol, 2-propanol and 1-hexanol with ethyl acetate in the temperature range 298.15–323.15 K. Thermal expansion coefficients α and their excess values αE were evaluated. The results were analyzed and discussed in terms of dependence of VE on chain length of alkanol and position of hydroxyl group and effect of temperature.