Title of article
Correlation between thermodynamic stability of zinc(II)tetraphenylporphyrine complexes with neutral molecules and physicochemical properties of the coordinated ligands
Author/Authors
Natalia Sh. Lebedeva، نويسنده , , Anatoly I. Vyugin، نويسنده , , Natalia A. Pavlycheva، نويسنده , , Elena V. Parfenyuk، نويسنده , , Olga I. Davidova، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2002
Pages
8
From page
179
To page
186
Abstract
The heats of interactions of zinc(II)tetraphenylporphyrine with 30 types of neutral molecules in benzene and carbon tetrachloride were measured using the calorimetric titration method. The thermodynamic characteristics of complex formation were calculated. The satisfactory multiparameter correlation of thermodynamic stability of the molecular complexes formed with physicochemical properties of the neutral molecules (electron pair donor ability, volume, electronic and orientational polarization) was obtained.
Keywords
thermodynamics , Molecular complexes , Metalloporphyrines
Journal title
Thermochimica Acta
Serial Year
2002
Journal title
Thermochimica Acta
Record number
1195722
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