Title of article
Phase evolution of a barium tin 1,2-ethanediolato complex to barium stannate during thermal decomposition
Author/Authors
Roberto K?ferstein، نويسنده , , Hans-Peter Abicht، نويسنده , , J?rg Woltersdorf، نويسنده , , Eckhard Pippel، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2006
Pages
8
From page
176
To page
183
Abstract
The thermal behaviour of [Ba(C2H6O2)4][Sn(C2H4O2)3] used as a BaSnO3 precursor, and its phase evolution during thermal decomposition are described. The initially formed transient barium tin oxycarbonate phase disintegrates into BaCO3 and SnO2, reacting subsequently to BaSnO3. The existence of the intermediate oxycarbonate phase is evidenced by Fourier transformed infrared (FT-IR), X-ray powder diffraction (XRD) and electron energy loss spectroscopy (EELS (ELNES)) investigations.
Keywords
Barium stannate , 1 , Oxycarbonate phase , Thermal decomposition , 2-Ethanediolato complex
Journal title
Thermochimica Acta
Serial Year
2006
Journal title
Thermochimica Acta
Record number
1197153
Link To Document