Title of article
The standard enthalpies of formation of proline stereoisomers
Author/Authors
Iulia Contineanu، نويسنده , , Ana Neacsu، نويسنده , , Roxana Zgîrian، نويسنده , , Speran?a T?n?sescu، نويسنده , , ?tefan Peri?anu، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2012
Pages
5
From page
31
To page
35
Abstract
The combustion calorimetry and differential scanning calorimetry (DSC) techniques have been employed in order to obtain the thermochemical properties of l-, d-enantiomers and racemic mixture of proline.
The large negative values of the enthalpies of formation of the investigated compounds reveal their high stability. The thermal behavior of the compounds was studied by means of DSC in the temperature range between ambient and 250 °C. A combined transformation–melting and decomposition is occurring on heating. The decomposition mechanism is discussed in relationship with the data obtained by means of DSC.
Keywords
Racemic , Enthalpy of combustion , Formation , DSC , Decomposition , proline , Zwitterion
Journal title
Thermochimica Acta
Serial Year
2012
Journal title
Thermochimica Acta
Record number
1200047
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