Title of article
Determination of the solubility, dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate in different organic solvents
Author/Authors
Wei Liu، نويسنده , , Li Xu، نويسنده , , Yanxun Li، نويسنده , , Tingliang Luo، نويسنده , , Guoji Liu، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2012
Pages
6
From page
89
To page
94
Abstract
The solubility of 3-pentadecylphenyl acrylate in n-butanol, toluene, acetone, dichloromethane, n-heptane and ethyl acetate were measured at the temperatures ranging from 273.15 to 297.15 K at atmospheric pressure using a laser detecting system. The solubility data were correlated by the modified Buchowski–Ksiazczak λh equation and Apelblat equation. The calculated results show that the correlation of the modified Apelblat equation has less deviation than that of the λh equation. The dissolution enthalpy and entropy of 3-pentadecylphenyl acrylate were predicted with the solubility data using van’t Hoff equation.
Keywords
3-Pentadecylphenyl acrylate , Solid–liquid equilibrium , Solubility , Dissolution enthalpy , Dissolution entropy
Journal title
Thermochimica Acta
Serial Year
2012
Journal title
Thermochimica Acta
Record number
1200182
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