Enthalpies of solution of DL-α-Alanyl-DL-α-Valine in aqueous solution of amides at 298.15 K

The enthalpies of solution of DL-α-Alanyl-DL-α-Valine in aqueous solution of formamide, N-methylformamide, N,N-dimethylformamide, N,N-diethylformamide and N,N-dimethylacetamide were determined by calorimetry at 298.15 K over the concentration range x2 = 0–0.4 mole fractions. Standard enthalpies of solution ΔsolHm° and transfer ΔtrHm° from water to mixed solvents were computed. The enthalpy coefficients of pairwise DL-α-Alanyl-DL-α-Valine–amide interactions were calculated. The interrelation between the enthalpy characteristics of solution (transfer) of DL-α-Alanyl-DL-α-Valine and the structure and physicochemical characteristics of solvents, as well as the composition of mixtures were revealed.