Title of article
Application of thermal analysis to study the macroredox polymerization of styrene with hydroxy-terminated polybutadiene
Author/Authors
Joshy Simon، نويسنده , , Anjali Bajpai، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
13
From page
2077
To page
2089
Abstract
Ceric ammonium nitrate–hydroxy-terminated polybutadiene macroredox initiator has been investigated for the polymerization of styrene in nitric acid medium at 35 °C. Water inhibited the polymerization of styrene using this macroredox system. The products obtained were crosslinked and insoluble in water and organic solvents. A probable mechanism for the copolymerization reaction has been inferred from differential scanning calorimetry. Kinetic parameters for thermal degradation have been calculated by thermogravimetry (TG).
Keywords
Hydroxy-terminated polybutadiene , polystyrene , Macroredox polymerization , Copolymerization , ceric ammonium nitrate , thermal analysis
Journal title
European Polymer Journal(EPJ)
Serial Year
2003
Journal title
European Polymer Journal(EPJ)
Record number
1212186
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