Title of article
Dissociative adsorption of HCOOH, CH3OH, and CH2O on MCM-41
Author/Authors
Meng-Tso Chen، نويسنده , , Yi-Shiue Lin، نويسنده , , Yu-Feng Lin، نويسنده , , Hong-Ping Lin، نويسنده , , Jong-Liang Lin *، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
5
From page
259
To page
263
Abstract
Adsorption and surface reactions of HCOOH, CH3OH, and CH2O on siliceous mesoporous MCM-41 have been investigated by Fourier-transform infrared spectroscopy. CH2O decomposes on the surface to form adsorbed CH3O and HCOO (an analog of Cannizzaro disproportionation) which are identified by dissociative adsorption of CH3OH and HCOOH. In addition, CH3OH is sequentially oxidized to CH2O and HCOO on MCM-41. These types of reactions for CH2O and CH3OH on MCM-41 have not been observed on amorphous SiO2 without a mesoporous structure.
Journal title
Journal of Catalysis
Serial Year
2004
Journal title
Journal of Catalysis
Record number
1223498
Link To Document