Title of article
MICELLAR CATALYTIC EFFECTS IN THE OXIDATION OF METHYL PHENYL SULFIDE WITH HYDROGEN PEROXIDE AND THE HYDROGEN PEROXOCARBONATE ANION
Author/Authors
Savelova، V.A. نويسنده , , Popov، A.F. نويسنده , , Razumova، N.G. نويسنده , , Vakhitova، L.N. نويسنده , , Skrypka، A.V. نويسنده , , Taran، N.A. نويسنده , , Zhil’tsova، S.V. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
8
From page
287
To page
294
Abstract
The kinetics and mechanism of the catalysis by ammonium hydrogen carbonate oxidation of methyl phenyl sulfide with hydrogen peroxide has been investigated. Using the classical pseudo-phase model of micellar catalysis, the basic parameters of the catalytic process have been determined: the binding constants of H2O2, the HCO4 ^-anion, and the substrate to the surface of the micelles, and also the second order rate constants for the oxidation of methyl phenyl sulfide in the micellar phase.
Keywords
Oxidation , micellar catalysis , Hydrogen peroxide , the hydrogen peroxocarbonate anion
Journal title
Theoretical and Experimental Chemistry
Serial Year
2006
Journal title
Theoretical and Experimental Chemistry
Record number
122408
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