Title of article :
The influence of the acid strength of P-modified and of HNO3-dealuminated HZSM-5 on the selectivity for the formation of propene was examined in the conversion of 1-butene. Under the appropriate amount of total acid sites, the reaction pathways of dimeriz
Author/Authors :
Bo Weng، نويسنده , , Siqi Liu، نويسنده , , Nan Zhang، نويسنده , , Zirong Tang، نويسنده , , Yi-Jun Xu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
One-dimensional CdS nanowires-carbon nanotubes nanocomposites (1D–1D CdS NWs-CNT NCs) with different weight addition ratios of CNT have been synthesized by a very simple room temperature self-assembly method, which is afforded by electrostatic attractive interaction between positively charged CdS NWs and negatively charged CNT in an aqueous solution. Importantly, the CdS NWs-CNT NCs exhibit remarkably enhanced photoactivity toward selective reduction of aromatic nitro organics in water under visible light irradiation as compared to bare CdS NWs. The significantly enhanced photoactivity is attributed to the integrated factors of the unique 1D–1D morphology associated with CdS NWs and CNT, the efficient retardation of recombination of the photoexcited electron–hole pairs, and the enhanced visible light absorption intensity. Besides, the CdS NWs-CNT NCs exhibit higher photoactivity than CdS NWs-reduced graphene oxide (CdS NWs-RGO NCs), toward selective reduction of aromatic nitro organics. Therefore, this work not only offers a very simple room temperature approach to synthesize highly efficient 1D semiconductor-1D CNT composite photocatalyst, but also gives an example that RGO cannot readily manifest its unique and prominent advantage over CNT for specific photocatalytic application, thus underpinning the importance of rationally utilizing the carbon materials (e.g., 1D CNT, 2D RGO) to design more efficient carbon-semiconductor composite photocatalyst.
Keywords :
1-Butene catalytic cracking , ZSM-5 , Reaction pathways , Acid strength , Propene
Journal title :
Journal of Catalysis
Journal title :
Journal of Catalysis