Title of article
MODIFIED LANGMUIR ISOTHERM FOR THE DESCRIPTION OF CLUSTER ADSORPTION ON SURFACE LYOPHILIC CENTERS
Author/Authors
Aksenenko، E.V. نويسنده , , Tarasevich، Yu.I. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
7
From page
295
To page
301
Abstract
An adsorption isotherm that generalizes the Langmuir equation for the cluster adsorption of several interacting molecules at one center is proposed. In the case of the adsorption of water molecules at surface hydroxyl groups on modified silica it was shown that the energy and structure characteristics of such a system, determined by the ab initio method, agree with the experimental data and lead to satisfactory agreement with the parameters of the proposed isotherm.
Keywords
Adsorption , ab initio modelling , modified silochrome , hydrophilic centers , generalized Langmuir isotherm
Journal title
Theoretical and Experimental Chemistry
Serial Year
2005
Journal title
Theoretical and Experimental Chemistry
Record number
122464
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