Title of article
Suppressing CO formation by anion adsorption and Pt deposition on TiO2 in H2 production from photocatalytic reforming of methanol
Author/Authors
Guopeng Wu، نويسنده , , Tao Chen، نويسنده , , Xu Zong، نويسنده , , Hongjian Yan، نويسنده , , Guijun Ma، نويسنده , , Xiuli Wang، نويسنده , , Qian Xu، نويسنده , , Donge Wang، نويسنده , , Zhibin Lei، نويسنده , , Can Li، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
225
To page
227
Abstract
H2 with ultra-low CO concentration less than 10 ppm was produced via photocatalytic reforming of methanol on Pt/TiO2 catalyst adsorbed with sulfate or phosphate ion. The platinum loaded on TiO2 not only enhances the rate of H2 production but also considerably suppresses CO formation. The sulfate and phosphate ions adsorbed on TiO2 were found to further suppress the CO formation, without evidently decreasing the rate of H2 production.
Keywords
entropy , Compensation effect , Enthalpy , Intrazeolitic concentration , Monomolecular alkane activation , Confinement effects
Journal title
Journal of Catalysis
Serial Year
2008
Journal title
Journal of Catalysis
Record number
1225291
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