Fuel cell performance and characterization of 1-D carbon-supported platinum nanocomposites synthesized in supercritical fluids

We present Pt particle size and fuel cell results for carbon black, carbon fibers, and single-walled carbon nanotubes (SWCNTs). The study investigated how high-temperature liquid and supercritical fluid synthesis conditions could influence the Pt particle size and fuel cell performance of these nanocomposite catalyst materials. High-temperature methanol is a suitable medium for Pt particle size deposition, generating smaller particles (90% measuring ⩽5 nm). The addition of a surfactant, such as sodium dodecyl sulfate, to the fluid medium improved the fuel cell performance and Pt utilization of all 3 supports by 27 to 63%, with the best catalyst material, Pt/SWCNTs, having a peak power density of 449 mW/cm2. This synthesis technique was a very fast (<5 min) process with no reactor sidewall effects on Pt particle size or yield.