Title of article :
Insights into the nature of iron-based Fischer–Tropsch catalysts from quasi in situ TEM-EELS and XRD
Author/Authors :
S. Janbroers، نويسنده , , J.N. Louwen، نويسنده , , H.W. Zandbergen، نويسنده , , P.J. Kooyman، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2009
Pages :
8
From page :
235
To page :
242
Abstract :
Although assumed to be iron carbide, the active phase of iron-based Fischer–Tropsch catalysts remains unresolved. An important issue is the air-sensitivity of the active catalysts. In this model study, exposure to air is prevented completely by performing both XRD and TEM-EELS in quasi in situ mode. Starting from hematite precursors, carburized catalysts contain mainly iron carbide of as yet unknown structure and some magnetite. The latter is not covered with amorphous carbon, whereas the carbide is covered. Carburized catalysts change significantly upon (controlled or uncontrolled) air exposure. During re-oxidation carbon is freed and deposited as a separate amorphous phase. When studying iron-based Fischer–Tropsch catalysts, exposure to air should be avoided completely.
Keywords :
Au particle size , Au/TiO2 , m-Dinitrobenzene hydrogenation , Rutile , Anatase
Journal title :
Journal of Catalysis
Serial Year :
2009
Journal title :
Journal of Catalysis
Record number :
1225829
Link To Document :
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