Thermal ageing of poly(ethylene oxide)/poly(3,4-ethylenedioxythiophene) semi-IPNs

The thermal stability study of a conducting semi-IPN has been reported. The thermo-oxidation of poly(ethylene oxide) (PEO)/poly(3,4-ethylenedioxythiophene) (PEDOT) semi-Interpenetrating Polymer Network (semi-IPN) was studied at 80 °C in open air. The degradation was followed by spectrophotometry in the visible and near infrared range, cyclic voltamperometry and thermogravimetric analysis. Fluorescence spectrophotometry allowed for the identification of OHradical dot by-product originated in the PEO network degradation by the use of a chemiluminescent probe, typically terephthalic acid. The formation of hydroxyl radicals damaged the PEDOT chains as checked by infrared spectroscopy. The mechanism of degradation is further confirmed (i) by introducing a radical scavenger or (ii) by performing a thermal ageing under inert atmosphere; in both cases the semi-IPN life-time is tremendously increased.