Transamidations in melt-mixed MXD6 and PA6I-6T polyamides: 1. Determination of the degree of randomness and block length by 1H-NMR analysis

The evaluation of the randomness degree and block length of polyamides after interchange reactions is a key issue to estimate the transamidation progress, which strongly influences the final properties of the materials. The polymers under examination are poly(m-xylylene adipamide) (MXD6) and poly(hexamethylene isophthalamide-co-terephthalamide) (PA6I-6T). They were blended by extrusion and then treated in differential scanning calorimeter (DSC) in order to improve transamidations and copolymer formation. The molecular structure of the final materials was analysed by means of an efficient, new and fast method based on 1H NMR analysis. The results were compared to those obtained by the more widely used 13C NMR analysis.