Title of article
A novel integrated process for the functionalization of methane and ethane: bromine as mediator
Author/Authors
Ivan M. Lorkovic، نويسنده , , Aysen Yilmaz، نويسنده , , Gurkan A. Yilmaz، نويسنده , , Xiao-Ping Zhou، نويسنده , , Leroy E. Laverman، نويسنده , , Shouli Sun، نويسنده , , Dieter J. Schaefer، نويسنده , , Michael Weiss، نويسنده , , Maria L. Noy، نويسنده , , C. Ian Cutler، نويسنده , , Jeffrey H. Sherman، نويسنده , , Eric W. McFarland، نويسنده , , Galen D. Stucky، نويسنده , , Peter C. Ford، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
6
From page
317
To page
322
Abstract
We describe a novel, integrated multi-step process for the partial oxidation of alkanes to alcohols, ethers or olefins using O2 as oxidant. The sequential transformations are (1) alkane bromination to alkyl bromide(s) and HBr, (2) reaction of this mixture with solid metal oxide (MO) to neutralize the HBr and to generate oxygenated products or olefins plus solid metal bromide, and (3) oxidation of the spent solid with O2 to regenerate the metal oxide and Br2 for reuse.
Keywords
Bromine-mediated , metal oxide , Alkane , partial oxidation
Journal title
CATALYSIS TODAY
Serial Year
2004
Journal title
CATALYSIS TODAY
Record number
1232297
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