Title of article
Environmentally friendly [Pd/Cu]-catalysed C3-alkenylation of free NH-indoles
Author/Authors
Laurent Djakovitch، نويسنده , , Pascal Rouge، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
10
From page
90
To page
99
Abstract
A new eco-efficient and environmentally friendly palladium/copper catalytic procedure for the C3-alkenylation of free NH-indoles is reported. Using homogeneous or heterogeneous heterobimetallic [Pd/Cu]-catalysts under mild reaction conditions (10 mol% Pd-catalyst and 10 mol% Cu-catalyst, 70 °C, air), substituted indoles are fully (58–82% isolated yields) and selectively (75–100% selectivity) converted to the expected 2-substituted-3-vinylindoles.
Keywords
3-Vinylindoles , oxidative coupling , Palladium–copper bimetallic catalysts , Zeolites
Journal title
CATALYSIS TODAY
Serial Year
2009
Journal title
CATALYSIS TODAY
Record number
1236725
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