• Title of article

    Environmentally friendly [Pd/Cu]-catalysed C3-alkenylation of free NH-indoles

  • Author/Authors

    Laurent Djakovitch، نويسنده , , Pascal Rouge، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2009
  • Pages
    10
  • From page
    90
  • To page
    99
  • Abstract
    A new eco-efficient and environmentally friendly palladium/copper catalytic procedure for the C3-alkenylation of free NH-indoles is reported. Using homogeneous or heterogeneous heterobimetallic [Pd/Cu]-catalysts under mild reaction conditions (10 mol% Pd-catalyst and 10 mol% Cu-catalyst, 70 °C, air), substituted indoles are fully (58–82% isolated yields) and selectively (75–100% selectivity) converted to the expected 2-substituted-3-vinylindoles.
  • Keywords
    3-Vinylindoles , oxidative coupling , Palladium–copper bimetallic catalysts , Zeolites
  • Journal title
    CATALYSIS TODAY
  • Serial Year
    2009
  • Journal title
    CATALYSIS TODAY
  • Record number

    1236725