Pore geometry influence on the deactivation behavior of Ni-based catalysts for simultaneous production of hydrogen and nanocarbon

Pore geometry of Ni-containing Mg–Al–O mixed oxide catalysts could be controlled by varying the Ni content in the synthesis. Low Ni content may lead to the catalysts having mesopores with shape cylinder and narrow pore size distribution; high Ni content results in the catalyst having pores with shape ink-bottle and a wide pore size distribution. In methane decomposition to produce hydrogen and nanocarbon, the 50 wt.% Ni/Mg–Al–O catalyst was rapidly deactivated after 2 h of reaction; however, the catalysts with 15 and 25 wt.% of Ni showed much longer lifetime, which can be explained by assuming a new modal related to pore geometry of the catalysts.