Examination of Solidification Pathways and the Liquidus Surface in the Nb-Ti-Al System

The solidification pathways, subsequent solid-state transformations, and the liquidus surface in the Nb-TiAl system have been examined as part of a larger investigation of phase equilibria in Nb-Ti-Al intermetallic alloys. Fifteen alloys ranging in composition from 15 to 40 at. pct Al, with Nb to Ti ratios of 4:1, 2:1, 1.5:1, 1:1, and 1:1.5, were prepared by arc melting and the as-cast microstructures were characterized by optical microscopy (OM), microhardness, X-ray diffraction (XRD), differential thermal analysis (DTA), backscattered electron imaging (BSEI), electron probe microanalysis (EPMA), and transmission electron microscopy (TEM). The results indicate that the range of primary ? solidification is much wider than that indicated in previously reported liquidus surfaces, both experimental and calculated. Differential thermal analysis has identified the existence of a ? to s + ? transformation in three alloys where it was previously thought not to exist; confirmation was provided by high-temperature vacuum heat treatments in the single-phase ? region followed by rapid quenching. The location of the boundary between the ?, s, and d primary solidification fields has been redefined. A massive ? -> d transformation, which was observed in the cast microstructure of a Nb-25Ti-25Al alloy, was repeatable through cooling following homogenization. A ? ->d + s eutectoid-like transformation in the 25 at. pct Al alloys, was detected by DTA and evaluated through microstructural analysis of heat-treated samples. Trends in the ? phase with variations in composition were established for both lattice parameters and microhardness. As a result of this wider extent of the primary ? solidification field, a greater possibility exists for microstructural control through thermal processing for alloys consisting of either s + ?, ? + s, or ? + d phases.