Solubility limits and microwave dielectric properties of Ba6−3xSm8+2xTi18O54 solid solution

Upper and lower solubility limits in Ba6−3xSm8+2xTi18O54 tungsten bronze ceramics were determined by Rietveld refinement of XRD data combined with backscattered electron images, and the variation tendency of microwave dielectric characteristics was also investigated. The upper solubility limit was confirmed as x = 2/3, while the lower solubility limit was determined as 1/4 instead of the previously reported one x = 3/10. The dielectric constant of Ba6−3xSm8+2xTi18O54 ceramics decreases monotonically with increasing x, while the small temperature coefficient of resonant frequency with complex variation tendency is observed for the compositions 1/2 ≤ x ≤ 4/5. The Qf value increases at first, reaches the maximum around x = 2/3, and turns to decrease for x > 7/10.