• Title of article

    LSCM–YSZ nanocomposites for a high performance SOFC anode

  • Author/Authors

    Inyong Jung، نويسنده , , Daehee Lee، نويسنده , , Seong Oh Lee، نويسنده , , Dongha Kim، نويسنده , , Joosun Kim، نويسنده , , Sang Hoon Hyun، نويسنده , , Jooho Moon، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2013
  • Pages
    6
  • From page
    9753
  • To page
    9758
  • Abstract
    La0.75Sr0.25Cr0.5Mn0.5O3−δ (LSCM) is a promising Ni-free anode material with reliable performance. LSCM retains excellent stability in both oxidizing and reducing environments at high operating temperatures, which makes it adoptable as solid oxide fuel cell (SOFC) anodes. However, the relatively inferior catalytic activity compared to Ni composite anodes limits the applicability in SOFC systems. Nanocomposite La0.75Sr0.25Cr0.5Mn0.5O3−δ–Y0.16Zr0.84O1.92 (LSCM–YSZ) anodes are investigated to improve the catalytic activity by effective dispersion of LSCM nanoparticles on stable YSZ backbones. LSCM–YSZ nanocomposite powders were synthesized via a polymerizable complex method. LSM–YSZ|yttria stabilized zirconia (YSZ)|LSCM–YSZ unit cells were characterized by electrochemical impedance spectroscopy and a current interruption method. Compositional mapping analysis on the LSCM–YSZ nanocomposite anode demonstrates uniform dispersion of LSCM nanoparticles and phase connectivity between LSCM and YSZ, resulting in a lower electrode polarization resistance of 1.82 Ω cm2 and greater peak power density of 177 mW cm−2 at 850 °C.
  • Keywords
    perovskite anode , solid oxide fuel cells , Nanocomposite
  • Journal title
    Ceramics International
  • Serial Year
    2013
  • Journal title
    Ceramics International
  • Record number

    1275429