Mechanical, morphological and dielectric properties of sintered mullite ceramics at two different heating rates prepared from alkaline monophasic salts

The sintering behavior of nanocrystalline orthorhombic mullite powders was investigated. The changes in microstructure, mechanical and dielectric properties with two different heating rates were explained. Microstructural characteristics depending on heating rate were explained at different sintering temperatures. Dielectric properties of prepared mullite nanocomposites were studied to examine the synthesized mullite ceramics as high permittivity materials in the microwave range. It was indicated that a sharp decrease in bulk density was observed at 1600 °C due to the exaggerated growth of mullite grains. Moreover, a maximum hardness value of 4.97 GPa was obtained at 1600 °C with slow heating rate (5 °min−1). The DC electrical resistivity with a slow heating rate at 1300 °C was approximately three times the value of the mullite sample sintered with a fast heating rate (30 °min−1). The minimum dielectric loss of about 0.017 at 1.5 GHz was achieved at a sintering temperature of 1500 °C with a slow heating rate.