The mobility, partitioning and degradation of atrazine and simazine in the salt marsh environment

The transfer of the s-triazine herbicides onto a salt marsh and their subsequent behaviour and fate has been investigated in a series of laboratory-based experiments. The results indicate that atrazine and simazine enter the marsh system and undergo negligible adsorption onto suspended solids. Herbicide accumulation within the sediment compartment was thought to be due to other mechanisms such as partitioning into the surface microlayer, or association with sediment flocs. s-Triazine mobility within the sediment was dictated by compound and sediment type, reflecting greater mobility in the mud flat than the vegetated marsh sediment. The majority of the herbicides were, however, retained in the uppermost layers of the sediment profile indicating that salt marsh sediments act as a sink for these compounds. Although degradation rates in the sediment were relatively rapid, detectable levels of the parent compounds were still evident after 71 days, which implies that these compounds may persist in salt marsh sediments. The absence of degradation in the aqueous phase implies that adsorption to particulate matter is a prerequisite for the degradation of the s-triazine herbicides.