Early Contamination by Heavy Metals of the Guadalquivir Estuary After the Aznalcóllar Mining Spill (SW Spain)

The Guadalquivir estuary was impacted by the accidental release of 5 million cubic meters of acid waste from the processing of pyrite ore (25 April 1998). The waste entered ecologically sensitive and protected areas such as the National Park of Doñana. Here are presented the results obtained from a time sequence of different sampling sites in the estuary and in the surrounding areas from May to September 1998. Water, suspended solids and sediments were analysed for six different metals (Fe, Mn, Zn, Cd, Pb, Cu). Also, the concentration of the metals in the different geochemical sediment fractions was determined as a means of assessing bioavailability. The results obtained during the first weeks after the incident show high concentrations of Zn. At the end of June a 10 000 m3 temporary water-treatment plant was constructed on site for depuration of the toxic waters. The results obtained in August and September show a decrease in the metal concentrations measured in the estuary. Only concentrations of Zn were higher than sediment quality values proposed by various authors.