High temperature–pressure processing of mixed alanate compounds Original Research Article

Mixtures of light-weight hydrides and elements were investigated to increase the understanding of the chemical reactions that take place between various materials. This report details investigations we have made into mixtures that include NaAlH4, LiAlH4, MgH2, Mg2NiH4, alkali(ne) hydrides, and early third row transition metals (V, Cr, Mn). Experimental parameters such as stoichiometry, heat from ball milling versus hand milling, and varying the temperature of high pressure molten state processing were studied to examine the effects of these parameters on the reactions of the complex metal hydrides.