Title of article :
Methane formation during the iridium/iodide catalysed carbonylation of methanol
Author/Authors :
Talit Ghaffar، نويسنده , , Jonathan P.H. Charmant، نويسنده , , Glenn J. Sunley، نويسنده , , George E. Morris، نويسنده , , Anthony Haynes، نويسنده , , Peter M. Maitlis، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
[Ir(CO)2I3Me]− reacts with carboxylic acids or hydrogen (but not with mineral acids) at elevated temperature to cleave the iridium(III)–methyl bond liberating methane; a cyclic transition state is proposed for the reactions with RCOOH.
Keywords :
Methyl complexes , Bond cleavage , Catalytic carbonylation , iridium complexes , Methane
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
