Title of article
Synthesis and structural characterization of [(μ-H)Ru3(CO)8{μ-S(CH2)3SH}(μ-dppe)] and [Ru3(CO)5{μ2-S(CH2)3S}2(η2-dppe)] (dppe=Ph2PCH2CH2PPh2)
Author/Authors
Shariff E Kabir، نويسنده , , K.M.Abdul Malik، نويسنده , , Edward Rosenberg، نويسنده , , Tasneem A Siddiquee، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
140
To page
142
Abstract
The reaction of 1,3-propanedithiol with [Ru3(CO)10(μ-dppe)] (2) at 66°C afforded the thiolate complexes [(μ-H)Ru3(CO)8{μ-S(CH2)3SH}(μ-dppe)] (6) and [Ru3(CO)5{μ2-S(CH2)3S}2(η2-dppe)] (7) in 25 and 23% yields respectively. Compound 6 is formed by simple oxidative addition of one of the S–H bonds of 1,3-propanedithiol while the structurally unique 7 consists of an open triruthenium cluster with four terminal and one asymmetrically bridged carbonyl groups, two doubly bridged propanedithiolate ligands and a chelating dppe ligand.
Keywords
Cluster complexes , Dithiolate complexes , Ruthenium complexes , Diphosphine complexes , crystal structures
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314830
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