Title of article :
Thermal condensation of trinuclear lanthanide butoxides. Molecular structure of La5(μ5-O)(μ3-OtBu)4(μ-OtBu)4(OtBu)5
Author/Authors :
Stéphane Daniele، نويسنده , , Liliane G. Hubert-Pfalzgraf، نويسنده , , Peter B. Hitchcock، نويسنده , , Michael F. Lappert، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
Refluxing of Ln3(OtBu)9(tBuOH)2 (Ln=La, Nd, Yb) in toluene led to Ln5O(OtBu)13 which was characterised by X-ray diffraction in the case of lanthanum. Aggregates of higher nuclearity were obtained in similar conditions for yttrium and praseodymium.
Keywords :
Lanthanides complexes , Oxo complexes , crystal structures , Yttrium , Alkoxide complexes
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
