Title of article
Formation of diastereomeric clusters (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} in the reaction of diallylsulfide with (μ-H)2Os3(CO)10
Author/Authors
Vladimir P Kirin، نويسنده , , Vladimir A Maksakov، نويسنده , , Alexander V Virovets، نويسنده , , Anatoliy V Golovin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
224
To page
226
Abstract
The interaction of (μ-H)2Os3(CO)10 with diallylsulfide S(Allyl)2 results in the formation of (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} (two diastereomers, 2a,b) and Os3(CO)10{η3(S,C,C)-S(Allyl)CH2CHCH2}. The crystal and molecular structures of 2a have been determined by X-ray analysis.
Keywords
Diastereomers , crystal structures , Triosmium clusters , Allylsulfide complexes , Cluster complexes , Osmium complexes , Hydrogenation , Isomerization
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314854
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