• Title of article

    Formation of diastereomeric clusters (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} in the reaction of diallylsulfide with (μ-H)2Os3(CO)10

  • Author/Authors

    Vladimir P Kirin، نويسنده , , Vladimir A Maksakov، نويسنده , , Alexander V Virovets، نويسنده , , Anatoliy V Golovin، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    3
  • From page
    224
  • To page
    226
  • Abstract
    The interaction of (μ-H)2Os3(CO)10 with diallylsulfide S(Allyl)2 results in the formation of (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} (two diastereomers, 2a,b) and Os3(CO)10{η3(S,C,C)-S(Allyl)CH2CHCH2}. The crystal and molecular structures of 2a have been determined by X-ray analysis.
  • Keywords
    Diastereomers , crystal structures , Triosmium clusters , Allylsulfide complexes , Cluster complexes , Osmium complexes , Hydrogenation , Isomerization
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2000
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1314854