Title of article
Highly diastereoselective cyclopalladation of α-ferrocenylethylphosphine: X-ray study of the first phosphapalladacycle of planar chirality
Author/Authors
Valery V Dunina، نويسنده , , Olʹga N Gorunova، نويسنده , , Michail V Livantsov، نويسنده , , Yuri K. Grishin، نويسنده , , Lyudmila G Kuzʹmina، نويسنده , , Nadezhda A Kataeva، نويسنده , , Andrei V. Churakov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
354
To page
357
Abstract
First planar chiral phosphapalladacycle was prepared in diastereomerically pure state via direct cyclopalladation of the di-tert-butyl-1-ferrocenylethylphosphine. The palladacycle structure was confirmed by 1H NMR spectra; relative configuration of central and planar chirality was determined by an X-ray diffraction study of the triphenylphosphine adduct.
Keywords
crystal structures , planar chirality , conformation , Phosphapalladacycle , Ferrocenylethylphosphine
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314888
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