Title of article
Investigation of the tetracarbonatozirconate ion by electrospray mass spectrometry in aqueous media
Author/Authors
Anne Veyland، نويسنده , , Laurent Dupont، نويسنده , , Jean-Claude Pierrard، نويسنده , , Jean Rimbault، نويسنده , , Michel Aplincourt، نويسنده , , Ludovic Devoldere، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
8
From page
600
To page
607
Abstract
Reported here is the study of zirconium (IV) aqueous solutions in carbonate media by electrospray ionisation mass spectrometry (ESI–MS). Spectra analysis lead to consider the existence in the spray of the initial pseudomolecular labile species [Zr(CO3)4(HCO3)]5−, xH+, (6−x) K+ (or Na+). The existence of this species confirms the associative exchange mechanism of carbonate ions with [Zr(CO3)4]4− ion.
Keywords
Fragmentation , Carbonatozirconium complexes , mass spectrometry , Electrospray
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314947
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