Title of article :
Rhodium catalysed hydroformylation using diphenylphosphine functionalised carbosilane dendrimers
Author/Authors :
Debby de Groot، نويسنده , , Peter G. Emmerink، نويسنده , , Caroline Coucke، نويسنده , , Joost N.H Reek، نويسنده , , Paul C.J. Kamer، نويسنده , , Piet W.N.M. van Leeuwen، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
Diphenylphosphine functionalised carbosilane dendrimers Si((CH2)nSi(CH3)2(CH2PPh2))4 (n=2,3; generation 1–3) and Si((CH2)nSi(CH3)(CH2PPh2)2)4 (n=2,3; generation 1–2) have been synthesised and used as ligands in the rhodium catalysed hydroformylation of 1-octene. The activity of the system depends on the size and flexibility of the dendrimeric ligand.
Keywords :
hydroformylation , Rhodium , Catalysis , Carbosilane dendrimers , phosphines
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
