Title of article :
Pronounced effects of counterions on intramolecular electron transfer in 1′,1‴-dinaphthylmethylbiferrocenium cation
Author/Authors :
Teng-Yuan Dong، نويسنده , , Tzon-Jyi Lee، نويسنده , , Bor-Ruey Huang، نويسنده , , Shie-Ming Peng، نويسنده , , Gene-Hsiang Lee، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
The X-ray structure of 1′,1‴-dinaphthylmethylbiferrocenium BF4 has been determined. The 57Fe Mössbauer and EPR results of 1′,1‴-dinaphthylmethylbiferrocenium BF4 and PF6 salts are also reported. The relatively minor perturbations caused by the counterions have pronounced effects on the rate of intramolecular electron transfer.
Keywords :
Mixed-valence 1? , 1?-dinaphthylmethylbiferrocenium , Biferrocenium , Metallocene , Electron transfer
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
