Title of article :
Transmetallation. Synthesis of a novel acetato bridged low-spin Co(II)–Zn(II) heterodinuclear complex from an acetato bridged one-dimensional Zn(II) polymer
Author/Authors :
Goutam K. Patra، نويسنده , , Michael G.B. Drew، نويسنده , , Dipankar Datta، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
Reaction of Co(ClO4)2 · 6H2O with [Zn(dien) (CH3CO2)]n(ClO4)n (dien ≡ diethylene-triamine) in water in a specified proportion leads to the isolation of a novel heterodinuclear complex [(dien)Zn(μ-CH3CO2)(μ-H2O)2Co(dien)](ClO4)3, where the Co(II) centre is low-spin octahedral.
Keywords :
Zinc complexes , crystal structures , Transmetallation , Dinuclear complexes , Cobalt(II) complexes
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
