Title of article
Highly stable open frameworks of Ln–Cu (Ln=La, Ce) 3D coordination polymers containing spacious hexagon channels and unusual μ2-H2O bridges
Author/Authors
Qin-De Liu، نويسنده , , Jun-Ran Li، نويسنده , , Song Gao، نويسنده , , Baoqing Ma، نويسنده , , Fu-Hui Liao، نويسنده , , Qing-Zhong Zhou، نويسنده , , Kai-Bei Yu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
301
To page
304
Abstract
Novel 3D Ln–Cu heteronuclear complexes [Ln2Cu3(μ2-H2O)(DGA)6(H2O)3]·3H2O (Ln = La, Ce) containing unusual μ2-H2O bridges were formed by linking mononuclear units of [Ln(DGA)3] (H2DGA = diglycolic acid) by copper ions, to produce an open framework containing large amount of spacious hexagon channels with stable skeletons as demonstrated by thermogravimetric analysis (TGA) and X-ray diffraction (XRD) analysis.
Keywords
Heteronuclear , Coordination polymer , Open framework , Hydrogen bond
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315056
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