Title of article :
A novel protonated boranoamino acid amide derivative, (CH3)3N·BH2C(OH)N+HC2H5Cl−: A synthetic and structural investigation
Author/Authors :
Bernard F. Spielvogel، نويسنده , , Geeta Rana، نويسنده , , Kamesh Vyakaranam، نويسنده , , Andrew T. McPhail، نويسنده , , Fahim U. Ahmed، نويسنده , , Narayan S. Hosmane، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
The reaction between Me3N·BH2CONHC2H5 (1) and anhydrous HCl gas in diethyl ether resulted in the formation of an unprecedented salt, Me3N·BH2C(OH)N+HC2H5Cl− (2), whose crystal structure unambiguously shows that the amide hydrogen atom is oriented in trans configuration with respect to the hydroxyl group.
Keywords :
Cis–trans isomers , crystal structure , Protonation reaction , Boranoamino acid amide
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
