Title of article :
The first metal complex containing a silylated β-diketonate ligand: bis(2,2,6,6-tetramethyl-2-sila-3,5-heptanedionato) copper(II)
Author/Authors :
Kulbinder K. Banger، نويسنده , , Andrei Kornilov، نويسنده , , Rolf U. Claessen، نويسنده , , Eric T. Eisenbraun، نويسنده , , Alain E. Kaloyeros، نويسنده , , Paul J. Toscano، نويسنده , , John T. Welch، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
A facile preparation of 2,2,6,6-tetramethyl-2-sila-3,5-heptanedione (tmshdH), exemplar of a new class of ligands, the sila-β-diketones, has been developed. Silicon substitution in the ligands has profound effects on the volatility, thermal properties, crystal packing, and electronic spectrum of the homoleptic Cu(II) complex, Cu(tmshd)2.
Keywords :
Copper complex , UV/Vis spectroscopy , Chemical vapor deposition , Volatile complexes , crystal structure , Sila-?-diketone
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
