Title of article :
A three-dimensional framework of dimeric copper(II) acetate linked by coordinated sodium cations
Author/Authors :
Chuande Wu، نويسنده , , Can-Zhong Lu، نويسنده , , Wen-Bin Yang، نويسنده , , Honghui Zhuang، نويسنده , , Jinshun Huang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
The reaction of a DMSO solution of Cu(OCOCH3)2·H2O with CH3COONa·3H2O in the presence of acetate acid gives the formation of sodium cations linking six-coordinated copper(II) acetates into microporous network structure, NaHCu2(OCOCH3)6 1. The powder ESR of 1 reveals that there might exist exchange interactions between these copper(II) cations.
Keywords :
Trans-influence effects , ESR spectrum , Network structure , Dimeric copper(II) acetate
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications