Title of article
Synthesis and structure of a high-nuclearity oxomolybdenum(V) complex, [Mo12O28(OC2H5)4(C6H7N)8]
Author/Authors
Barbara Modec، نويسنده , , Jurij V. Bren?i?، نويسنده , , Jon Zubieta*، نويسنده , , Pamela J. Hagrman، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
537
To page
540
Abstract
(PyH)[MoOBr4(H2O)]·2/3PyHBr (PyH+=pyridinium cation, C5H5NH+) yielded upon the solvothermal reaction with ethanol and 4-methylpyridine (4-MePy, C6H7N) a novel oxoethoxomolybdenum(V) cluster, [Mo12O28(OC2H5)4(4-MePy)8] 1. Molybdenum atoms are grouped into six MoV2 pairs linked by single metal–metal bonds. Three crystallographically independent Mo–Mo distances are 2.5578(14), 2.5981(14) and 2.6489(16) Å.
Keywords
Clusters , Polyoxomolybdates , Alkoxo complexes , crystal structure , Pyridine complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315160
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