• Title of article

    Unusual reactions of ruthenium–polycyanocarbon complexes: formation of an η2-CNR ligand and cleavage of C(sp2)–CN bonds

  • Author/Authors

    Michael I. Bruce، نويسنده , , Brian W. Skelton، نويسنده , , Allan H. White، نويسنده , , Natasha N. Zaitseva، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    617
  • To page
    620
  • Abstract
    Unusual formation of an η2-bonded polycyanocarbon ligand from tetracyanoethene, C2(CN)4 (tcne) and the allylic ligand in Ru{η3-CHPhCHCCPh(CCPh)}(PPh3)Cp∗ (1), and migration of CN from the polycyanocarbon in Ru{C[C(CN)2]CPhC(CN)2}(dppm)Cp∗ (3), have been established by crystal structure determinations on Ru{C(CHCHPh)CPhC[CPhC(CN)2]C(CN)(η2-CN)}(PPh3)Cp∗ (2) and Ru(CN){C(CN)C[CPhC(CN)2]PPh2CH2PPh2}Cp∗ (4), which are the respective products.
  • Keywords
    crystal structure , CN group migration , Cyanocarbon , Ruthenium
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2001
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315193

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1315193