• Title of article

    Solvent-induced supramolecular isomerism in homochiral silver benzimidazolates

  • Author/Authors

    Xun-Gao Liu، نويسنده , , Yanying Wang، نويسنده , , Yingying Hu a، نويسنده , , Zhi-Guo Gu، نويسنده , , Liang Shen، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2014
  • Pages
    5
  • From page
    103
  • To page
    107
  • Abstract
    Two pairs of enantiomers R-[Ag4(hebim)4] · 3DMAC (R-1), S-[Ag4(hebim)4] · 3DMAC (S-1), R-[Ag(hebim)] (R-2) and S-[Ag(hebim)] (S-2) [Hhebim = 2-(1-hydroxyethyl) benzimidazole] are reported. Complexes 1 and 2 are supramolecular isomers induced by solvent and are second harmonic generation (SHG) active. In addition, solid-state luminescent properties of 1 and 2 were investigated at room temperature.
  • Keywords
    Second harmonic generation , Supramolecular isomerism , Luminescence , Ag(I)
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2014
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315198