Title of article
Hydrothermal synthesis and structure of a bi-capped Keggin polyoxoanion, [AsIII2AsVMo8VIV4O40]5−
Author/Authors
Guoyou Luan، نويسنده , , Yangguang Li، نويسنده , , Enbo Wang، نويسنده , , Zhengbo Han، نويسنده , , Changwen Hu، نويسنده , , Ninghai Hu، نويسنده , , Hengqing Jia، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
3
From page
632
To page
634
Abstract
The title compound, [NH3CH2CH2CH2NH2][NH3CH2CH2CH2NH3]2[AsIII2AsVMo8VIV4O40]·5H2O, was hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Crystal data: monoclinic, C2/c, a=45.375(9) Å, b=11.774(2) Å, c=23.438(5) Å, β=96.62(3)°. X-ray crystallographic study showed that the crystal structure was constructed by bi-capped α-Keggin fragments [AsIII2AsVMo8VIV4O40]5− polyoxoanion.
Keywords
Polyoxometalate , Hydrothermal synthesis , Bi-capped Keggin , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315199
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