Title of article :
Synthesis of a ruthenium complex of a cyclic trifunctional η6, η1, η1-arene–diphosphine ligand by intramolecular dehydrofluorinative carbon–carbon coupling
Author/Authors :
Ronan M. Bellabarba، نويسنده , , Graham C. Saunders، نويسنده , , Sarah Scott، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
Treatment of the ruthenium complex cation [(η6-C6H3Me3-1,3,5)(RuCl(dfppe)]+ {dfppe=(C6F5)2PCH2CH2P(C6F5)2} with proton sponge yields [{η6,η1,η1-C6H3Me-5-[CH2-2-C6F4P(C6F5)CH2]2-1,3}RuCl]+ by stepwise intramolecular dehydrofluorinative carbon–carbon coupling.
Keywords :
Ruthenium , ?6-Arene , Phosphine , Dehydrofluorinative carbon–carbon coupling , Hybrid ligands
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications