Title of article :
A novel 3D metal–organic framework constructed from monosubstituted Keggin chains and metal–carboxylate chains
Author/Authors :
Xiuli Wang، نويسنده , , Na Han، نويسنده , , Hongyan Lin، نويسنده , , Jian Luan، نويسنده , , Aixiang Tian، نويسنده , , Danna Liu، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
A novel monosubstituted Keggin-type polyoxometalate (POM)-based metal–organic framework [Cu4IICu2I(pzca)6(HPCuMo11O39)(H2O)6]·2H2O (1) (pzca = 2-pyrazinecarboxylic acid) has been hydrothermally synthesized and characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction analysis. Compound 1 shows a (2,3,4,7)-connected three-dimensional framework with {4 · 62 · 9 · 102}{4 · 92}{42 · 69 · 87 · 103}{6 · 9 · 10}2{9}2 topology, which is constructed from the monosubstituted Keggin chains [HPCuMo11O39]n4n − and metal–carboxylate chains [Cu6(pzca)6]n4n +. The electrochemical behavior and photocatalytic activity of compound 1 have been investigated.
Keywords :
2-Pyrazinecarboxylic acid , Photocatalytic property , Electrochemical property , Monosubstituted polyoxometalate , Metal–organic framework
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
